{"id":13699,"date":"2025-07-14T10:49:30","date_gmt":"2025-07-14T02:49:30","guid":{"rendered":"https:\/\/li-on.biz\/?p=13699"},"modified":"2025-07-14T12:04:23","modified_gmt":"2025-07-14T04:04:23","slug":"reach-%e9%99%84%e9%8c%84-17-entry68-%e5%8d%b3%e5%b0%87%e6%9b%b4%e6%96%b0","status":"publish","type":"post","link":"https:\/\/li-on.biz\/zh\/reach-%e9%99%84%e9%8c%84-17-entry68-%e5%8d%b3%e5%b0%87%e6%9b%b4%e6%96%b0\/","title":{"rendered":"REACH \u9644\u5f55 17 entry68 \u5373\u5c06\u66f4\u65b0"},"content":{"rendered":"

\u6b27\u6d32\u59d4\u5458\u4f1a\u8ba4\u4e3a\u4f7f\u7528\u6216\u5236\u9020 C9-C14 PFCAs\u3001\u5176\u76d0\u7c7b\u4e0e\u4efb\u4f55\u76f8\u5173\u7269\u8d28\u4f1a\u5bf9\u4eba\u4f53\u5065\u5eb7\u53ca\u73af\u5883\u9020\u6210\u4e0d\u53ef\u63a5\u53d7\u7684\u98ce\u9669\u3002\u5728 2021 \u5e74 8 \u6708 4 \u65e5\u5b98\u65b9\u516c\u62a5\u4e2d\u516c\u544a\uff0c\u9884\u8ba1\u5c06 C9-C14 PFCAs\u3001\u5176\u76d0\u7c7b\u4e0e\u4efb\u4f55\u76f8\u5173\u7269\u8d28\u53d6\u4ee3\u539f\u5148\u9644\u5f55 17 \u7b2c 68 \u9879\uff0c\u9650\u5236\u5176\u4f5c\u4e3a\u7269\u8d28\u7684\u4f7f\u7528\u3001\u5728\u6df7\u5408\u7269\u4e2d\u53ca\u5728\u6210\u54c1\u4e2d\u7684\u603b\u6d53\u5ea6\u3002\u8be5\u6761\u4f8b\u5728\u5b98\u65b9\u516c\u62a5\u4e0a\u516c\u5e03\u4e4b\u65e5\u8d77\u7b2c 20 \u5929\u5f00\u59cb\u751f\u6548\u3002<\/p>\n\n\n\n

\"\u6b50\u6d32\u59d4\u54e1\u6703\u8a8d\u70ba\u4f7f\u7528\u6216\u88fd\u9020<\/figure>\n\n\n\n

REACH\u00a0\u9644\u5f55 17 entry68 \u4e2d\u9488\u5bf9\u4e8e C9-C14 PFCAs\u3001\u5176\u76d0\u7c7b\u4e0e\u4efb\u4f55\u76f8\u5173\u7269\u8d28\u7684\u76f8\u5173\u89c4\u8303\uff0c\u4e3b\u8981\u5982\u4e0b\uff1a<\/p>\n\n\n\n

\u5316\u5b66\u7269\u8d28\u00a0(\u7fa4\u7ec4)\u6216\u6df7\u5408\u7269\u4e2d\u4e4b
\u5316\u5b66\u7269\u8d28\u540d\u79f0)
<\/td>		\u9650\u5236\u6761\u4ef6<\/td><\/tr>
68.\u00a0\u901a\u5f0f\u4e3a\u00a0Cn<\/sub>F2n+1<\/sub>-C(= O)OH\u00a0\u7684\u76f4\u94fe\u548c\u652f\u94fe\u5168\u6c1f\u7fa7\u9178\uff0c\u5176\u4e2d\u00a0n = 8\u30019\u300110\u300111\u300112\u00a0\u6216\u00a013\uff08C9-C14 PFCA\uff09\uff0c\u5305\u62ec\u5176\u76d0\u7c7b\u53ca\u4efb\u4f55\u7ec4\u5408\uff1b

\u4efb\u4f55\u5177\u6709\u901a\u5f0f\u4e3a\u00a0Cn<\/sub>F2n+1<\/sub>\u2013\u00a0\u5168\u6c1f\u57fa\u56e2\u7684\u00a0C9-C14 PFCA\u00a0\u76f8\u5173\u7269\u8d28\u4e0e\u53e6\u4e00\u4e2a\u78b3\u539f\u5b50\u76f4\u63a5\u76f8\u8fde\uff0c\u5176\u4e2d\u00a0n = 8\u30019\u300110\u300111\u300112\u00a0\u00a0\u6216\u00a0 13\uff0c\u5305\u62ec\u5176\u76d0\u7c7b\u53ca\u4efb\u4f55\u7ec4\u5408\uff1b

\u4efb\u4f55\u5177\u6709\u901a\u5f0f\u4e3a\u00a0Cn<\/sub>F2n+1<\/sub>\u2013\u00a0\u5168\u6c1f\u57fa\u56e2\u7684\u00a0C9-C14 PFCA\u00a0\u76f8\u5173\u7269\u8d28\u5176\u4e0d\u76f4\u63a5\u8fde\u63a5\u5230\u53e6\u4e00\u4e2a\u78b3\u539f\u5b50\u4f5c\u4e3a\u7ed3\u6784\u5143\u7d20\u4e4b\u4e00\uff0c\u5176\u4e2d\u00a0n = 9\u300110\u300111\u300112\u300113\u00a0\u6216\u00a014\uff0c\u5305\u62ec\u5176\u76d0\u7c7b\u53ca\u4efb\u4f55\u7ec4\u5408\u3002

\u4ee5\u4e0b\u7269\u8d28\u6392\u9664\u5728\u5916Cn<\/sub>F2n+1<\/sub>-X\uff0c\u5176\u4e2d\u00a0X = F\u3001Cl\u00a0\u6216\u00a0Br\uff0c\u4e14\u00a0n = 9\u300110\u300111\u300112\u300113\u00a0\u6216\u00a014\uff0c\u5305\u62ec\u5176\u4efb\u4f55\u7ec4\u5408\uff0cCn<\/sub>F2n+1<\/sub>-C(= O)OX\u2019\uff0c\u5176\u4e2dn> 13\u00a0\u4e14\u00a0X\u2019 =\u00a0\u4efb\u4f55\u57fa\u56e2\uff0c\u5305\u62ec\u76d0\u7c7b\u3002<\/td>		\u81ea2023\u5e742\u670825\u65e5\u8d77\uff0c\u4e0d\u5f97\u5236\u9020\u7269\u8d28\u6216\u4f5c\u4e3a\u7269\u8d28\u6295\u653e\u5e02\u573a\u3002\u81ea2023\u5e742\u670825\u65e5\u8d77\uff0c\u4e0d\u5f97\u88ab\u7528\u4e8e\u6216\u6295\u653e\u4e8e\u5e02\u573a\uff1a(a)\u00a0\u4f5c\u4e3a\u6210\u5206\u4e2d\u7684\u7269\u8d28\uff1b
(b)\u00a0\u6df7\u5408\u7269\uff1b
(c)\u00a0\u6210\u54c1\uff0c
\u9664\u975e\u7269\u8d28\u3001\u6df7\u5408\u7269\u6216\u6210\u54c1\u4e2dC9-C14 PFCA\u53ca\u5176\u76d0\u7c7b\u7684\u603b\u6d53\u5ea6\u5c0f\u4e8e25 ppb\u6216C9-C14 PFCA\u76f8\u5173\u7269\u8d28\u7684\u603b\u6d53\u5ea6\u5c0f\u4e8e260 ppb\u3002\u4f5c\u4e3a\u5bf9\u6bb5\u843d2\u7684\u8c41\u514d\uff0c\u5f53C9-C14 PFCA\u3001\u5176\u76d0\u7c7b\u4e0eC9-C14 PFCA\u76f8\u5173\u7269\u8d28\u5b58\u5728\u4e8e\u7269\u8d28\u4e2d\u4f5c\u4e3a\u8fd0\u8f93\u9694\u79bb\u4e2d\u95f4\u4f53\u65f6\uff0c\u5176\u603b\u6d53\u5ea6\u9650\u503c\u4e3a10 ppm\uff0c\u53ea\u8981\u6ee1\u8db3\u672c\u6cd5\u89c4\u7b2c18\uff084\uff09\u6761\uff08a\uff09\u81f3\uff08f\uff09\u70b9\u7684\u6761\u4ef6\uff0c\u5373\u53ef\u751f\u4ea7\u5168\u6c1f\u78b3\u94fe\u957f\u5ea6\u7b49\u4e8e\u6216\u5c0f\u4e8e6\u4e2a\u539f\u5b50\u7684\u6c1f\u5316\u7269\u3002\u59d4\u5458\u4f1a\u5e94\u4e0d\u8fdf\u4e8e2023\u5e748\u670825\u65e5\u5ba1\u67e5\u6b64\u9650\u5236\u3002\u6bb5\u843d2\u81ea2023\u5e747\u67084\u65e5\u8d77\u751f\u6548\u4e8e\uff1a\u7528\u4e8e\u4fdd\u62a4\u5de5\u4eba\u514d\u53d7\u5371\u5bb3\u5176\u5065\u5eb7\u548c\u5b89\u5168\u7684\u5371\u9669\u6db2\u4f53\u7684\u9632\u6cb9\u9632\u6c34\u7eba\u7ec7\u54c1\uff1b\u805a\u56db\u6c1f\u4e59\u70ef(PTFE)\u548c\u805a\u504f\u4e8c\u6c1f\u4e59\u70ef(PVDF)\u7684\u5236\u9020\uff0c\u7528\u4e8e\u751f\u4ea7\uff1a\u9ad8\u6027\u80fd\u3001\u8010\u8150\u8680\u7684\u6c14\u4f53\u8fc7\u6ee4\u819c\u3001\u6c34\u8fc7\u6ee4\u819c\u548c\u533b\u7528\u7eba\u7ec7\u54c1\u819c\uff1b\u5de5\u4e1a\u5e9f\u70ed\u4ea4\u6362\u8bbe\u5907\uff1b\u80fd\u591f\u9632\u6b62\u6325\u53d1\u6027\u6709\u673a\u5316\u5408\u7269\u548cPM 2.5\u9897\u7c92\u6cc4\u6f0f\u7684\u5de5\u4e1a\u5bc6\u5c01\u5242\u4f5c\u4e3a\u5bf9\u6bb5\u843d2\u7684\u8c41\u514d\uff0c\u57282025\u5e747\u67084\u65e5\u4e4b\u524d\uff0c\u5e94\u5141\u8bb8\u4f7f\u7528C9-C14 PFCA\u3001\u5176\u76d0\u7c7b\u4e0eC9-C14 PFCA\u76f8\u5173\u7269\u8d28\u4e8e\uff1a\u534a\u5bfc\u4f53\u5236\u9020\u4e2d\u7684\u5fae\u5f71\u6216\u8680\u523b\u5236\u7a0b\uff1b\u6d82\u5728\u80f6\u7247\u4e0a\u7684\u7167\u76f8\u6d82\u6599\uff1b\u4fb5\u5165\u6027\u548c\u690d\u5165\u5f0f\u533b\u7597\u5668\u68b0\uff1b\u5df2\u5b89\u88c5\u5728\u7cfb\u7edf\u4e2d\u7684\u7528\u4e8e\u6db2\u4f53\u71c3\u6599\u70df\u96fe\u6291\u5236\u548c\u6db2\u4f53\u71c3\u6599\u706b\u707e\uff08B\u7c7b\u706b\u707e\uff09\u7684\u706d\u706b\u6ce1\u6cab\uff0c\u5305\u62ec\u79fb\u52a8\u548c\u56fa\u5b9a\u7cfb\u7edf\uff0c\u4f46\u987b\u7b26\u5408\u4ee5\u4e0b\u6761\u4ef6\uff1a\u542b\u6709\u6216\u53ef\u80fd\u542b\u6709C9-C14 PFCAs\u3001\u5176\u76d0\u7c7b\u548cC9-C14 PFCA\u00a0\u76f8\u5173\u7269\u8d28\u7684\u6d88\u9632\u6ce1\u6cab\u4e0d\u5f97\u7528\u4e8e\u57f9\u8bad\u4eba\u5458\uff1b\u542b\u6709\u6216\u53ef\u80fd\u542b\u6709C9-C14 PFCAs\u3001\u5176\u76d0\u7c7b\u548cC9-C14 PFCA\u00a0\u76f8\u5173\u7269\u8d28\u7684\u6d88\u9632\u6ce1\u6cab\u4e0d\u5f97\u7528\u4e8e\u6d4b\u8bd5\uff0c\u9664\u975e\u6240\u6709\u91ca\u653e\u7269\u90fd\u88ab\u63a7\u5236\u5728\u5185\uff1b\u4ece2023\u5e741\u67081\u65e5\u8d77\uff0c\u4ec5\u5141\u8bb8\u5728\u53ef\u4ee5\u63a7\u5236\u6240\u6709\u91ca\u653e\u7269\u7684\u573a\u6240\u4f7f\u7528\u542b\u6709\u6216\u53ef\u80fd\u542b\u6709C9-C14 PFCAs\u3001\u5176\u76d0\u7c7b\u548cC9-C14 PFCA\u00a0\u76f8\u5173\u7269\u8d28\u7684\u6d88\u9632\u6ce1\u6cab\uff1b\u542b\u6709\u6216\u53ef\u80fd\u542b\u6709C9-C14 PFCAs\u3001\u5176\u76d0\u7c7b\u548cC9-C14 PFCA\u00a0\u76f8\u5173\u7269\u8d28\u7684\u6d88\u9632\u6ce1\u6cab\u5e93\u5b58\u5e94\u6839\u636e\u6cd5\u89c4(EU)2019\/1021\u7b2c5\u6761\u8fdb\u884c\u7ba1\u7406\u3002\u6bb5\u843d2(c)\u4e0d\u9002\u7528\u4e8e2023\u5e742\u670825\u65e5\u4e4b\u524d\u6295\u653e\u5e02\u573a\u7684\u7269\u54c1\u3002\u57282028\u5e748\u670825\u65e5\u4e4b\u524d\uff0c\u6bb5\u843d2\u4e0d\u9002\u7528\u4e8e\u52a0\u538b\u8ba1\u91cf\u5438\u5165\u5668\u7684\u7f50\u5934\u6d82\u5c42\u3002\u6bb5\u843d2(c)\u81ea2023\u5e7412\u670831\u65e5\u8d77\u9002\u7528\u4e8e\uff1a(a)\u00a0\u534a\u5bfc\u4f53\u672c\u8eab\uff1b
(b)\u00a0\u5305\u542b\u5728\u534a\u6210\u54c1\u548c\u6210\u54c1\u7535\u5b50\u8bbe\u5907\u4e2d\u7684\u534a\u5bfc\u4f53\u3002\u6bb5\u843d2(c)\u5e94\u81ea2030\u5e7412\u670831\u65e5\u8d77\u9002\u7528\u4e8e2023\u5e7412\u670831\u65e5\u524d\u6295\u653e\u5e02\u573a\u7684\u7535\u5b50\u8bbe\u5907\u5907\u4ef6\u6216\u66ff\u6362\u90e8\u4ef6\u4e2d\u4f7f\u7528\u7684\u534a\u5bfc\u4f53\u3002\u5728\u00a02024\u5e748\u670825\u65e5\u4e4b\u524d\uff0c\u5bf9\u542b\u5168\u6c1f\u70f7\u6c27\u57fa\u7684\u6c1f\u5851\u6599\u548c\u542b\u6c1f\u6a61\u80f6\u4e2dC9-C14 PFCAs\u7684\u603b\u548c\uff0c\u6bb5\u843d2\u6240\u63d0\u5230\u7684\u6d53\u5ea6\u9650\u5236\u5e94\u4e3a2 000 ppb\u3002\u81ea2024\u5e748\u670825\u65e5\u8d77\uff0c\u542b\u5168\u6c1f\u70f7\u6c27\u57fa\u7684\u6c1f\u5851\u6599\u548c\u542b\u6c1f\u6a61\u80f6\u4e2dC9-C14 PFCAs\u7684\u603b\u6d53\u5ea6\u9650\u5236\u4e3a100 ppb\u3002\u5728\u5236\u9020\u548c\u4f7f\u7528\u542b\u6709\u5168\u6c1f\u70f7\u6c27\u57fa\u7684\u6c1f\u5851\u6599\u548c\u542b\u6c1f\u6a61\u80f6\u8fc7\u7a0b\u4e2d\uff0c\u5e94\u907f\u514d\u6240\u6709C9-C14 PFCAs\u7684\u6392\u653e\uff0c\u5982\u679c\u4e0d\u53ef\u80fd\uff0c\u5e94\u5728\u6280\u672f\u548c\u5b9e\u9645\u53ef\u884c\u7684\u60c5\u51b5\u4e0b\u5c3d\u53ef\u80fd\u51cf\u5c11\u6392\u653e\u3002\u672c\u8c41\u514d\u4e0d\u9002\u7528\u4e8e\u6bb5\u843d2\u4e2d\u63d0\u5230\u7684\u6210\u54c1\u3002\u59d4\u5458\u4f1a\u5e94\u4e0d\u8fdf\u4e8e2024\u5e748\u670825\u65e5\u5ba1\u67e5\u6b64\u8c41\u514d\u3002\u6bb5\u843d2\u4e2d\u63d0\u5230\u7684C9-C14 PFCAs\u603b\u548c\u7684\u6d53\u5ea6\u9650\u5236\u5e94\u4e3a1000 ppb\uff0c\u5982\u679c\u8fd9\u4e9b\u7269\u8d28\u5b58\u5728\u4e8e\u901a\u8fc7\u7535\u79bb\u8f90\u5c04\u6216\u70ed\u964d\u89e3\u4ea7\u751f\u7684PTFE\u5fae\u7c73\u7c89\u4f53\u4e2d\uff0c\u4ee5\u53ca\u5728\u542b\u6709PTFE\u5fae\u7c73\u7c89\u4f53\u4e4b\u5de5\u4e1a\u6216\u4e13\u4e1a\u7528\u6df7\u5408\u7269\u548c\u6210\u54c1\u4e2d\u3002\u5728PTFE\u5fae\u7c73\u7c89\u4f53\u7684\u5236\u9020\u548c\u4f7f\u7528\u8fc7\u7a0b\u4e2d\uff0c\u5e94\u907f\u514d\u6240\u6709C9-C14 PFCAs\u7684\u6392\u653e\uff0c\u5982\u679c\u4e0d\u53ef\u80fd\uff0c\u5e94\u5728\u6280\u672f\u548c\u5b9e\u9645\u53ef\u884c\u7684\u60c5\u51b5\u4e0b\u5c3d\u53ef\u80fd\u51cf\u5c11\u3002\u59d4\u5458\u4f1a\u5e94\u4e0d\u8fdf\u4e8e2024\u5e748\u670825\u65e5\u5ba1\u67e5\u6b64\u8c41\u514d\u3002\u5c31\u672c\u6761\u76ee\u6240\u6307\u7684C9-C14 PFCA\u76f8\u5173\u7269\u8d28\u662f\u6307\u6839\u636e\u5176\u5206\u5b50\u7ed3\u6784\u88ab\u8ba4\u4e3a\u5177\u6709\u964d\u89e3\u6216\u88ab\u8f6c\u5316\u4e3aC9-C14 PFCAs\u6f5c\u529b\u7684\u7269\u8d28\u3002<\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n

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